I think its a great opener! Usually the Stones put one of their strongest songs as openers - i think at least in following cases:
Sympathy For The Devil(B
Gimme Shelter (LI
Brown Sugar (SF)
Rocks Off (Exile)
Start me up (TY)
Undercover Of The Night (U)
One Hit (To The Body) (DW)
Love Is Strong (VL)
Flip The Switch (B2
Rough Justice (AB